Emergency services were called to a serious accident just past Five Oaks on the way to Horsham this morning.
Reports say two vehicles were involved in the crash.
Eyewitnesses say one of them left the road and ended up overturned in a field where it caught fire.
The A264 was closed eastbound from the junction with the A29 until mid morning.
A South East Coast Ambulance Service representative said they were called to the scene at 7.10am.
One person was taken to Royal Sussex County Hospital.
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